The document discusses PostgreSQL's physical storage structure. It describes the various directories within the PGDATA directory that stores the database, including the global directory containing shared objects and the critical pg_control file, the base directory containing numeric files for each database, the pg_tblspc directory containing symbolic links to tablespaces, and the pg_xlog directory which contains write-ahead log (WAL) segments that are critical for database writes and recovery. It notes that tablespaces allow spreading database objects across different storage devices to optimize performance.