
The melting point and boiling point, intensive
physical properties. The melting point denotes the temperature
at which a substance changes from a solid to a liquid. At
the boiling point, a material changes from a liquid to a gas.
These two characteristic temperatures of a substance are measures
of the strength and the nature of the bonds that are formed
within a substance.
Form
|
Melting Point (Celcius)
|
Boiling Point (Celcius)
|
Diamond
|
3550
|
4827
|
Graphite
|
3652 - 3697 (sublimes)
|
4200
|
Amorphous
|
3652 - 3697 (sublimes)
|
4200
|
Buckminsterfullerene
|
|
|
Are diamonds really forever?
Contrary to DeBeer's claims, a diamond is certainly
not last forever. It is thermodynamically unstable relative
to graphite at ambient conditions. Theoretically, the diamond
you have is very slowly transforming into it's duller cousin
- graphite. The most stable allotropic form of carbon is graphite.
This is shown by looking at the free energy of formation,
D G°f.
The amount of energy required to transform one form of carbon
to another can be determined by the difference between their
heat of formation, D H°f,
values. The degree of disorder is measured by the entropy
value, S° ,of the carbon form.
Form |
D H°f
(KJ/mole) |
D G°f
(KJ/mole) |
S° (J/mole*K) |
C (gas) |
718.4 |
672.9 |
158.0 |
C (diamond) |
1.88 |
2.84 |
2.43 |
C (graphite) |
0.00 |
0.00 |
5.69 |
C (C60) |
|
|
|
The transformation between diamond and graphite require
extreme conditions.
How extreme must the conditions be to produce
diamonds?
Diamonds require extreme pressures and temperatures
to form. They are formed at a depth of between 100 km and
200 km below Earth's surface, with a temperature range of
900 to 1300 degrees Celsius and pressures of 45 - 60 kBars.
At ambient conditions (25 degrees Celcius and 1 Bar*) diamond
is metastable. We can hold diamonds in our hands because its
transformation to the graphite, the more stable form of carbon
at ambient conditions, is slow. The temperatures and pressures
at which the various forms of carbon are stable is shown below: